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'[EE]: Was copper, now Lead?'
2000\09\09@105613 by robertf

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Hi,

Has anyone looked into the effect of lead vapor emmited during soldering?
I heared lead sublimes and therefore will be around if there are any sources
around, i.e-computers, TVs, solder spool, etc.

regards,

Robert Francisco
{Original Message removed}

2000\09\09@134216 by Nigel Goodwin

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In message <001501c01a63$8293c260$180d53d1@c525lab>, robertf
<spam_OUTrobertfTakeThisOuTspamMICROBALANCE.COM> writes
>Hi,
>
>Has anyone looked into the effect of lead vapor emmited during soldering?
>I heared lead sublimes and therefore will be around if there are any sources
>around, i.e-computers, TVs, solder spool, etc.

I've recently being part of a test by the 'Health and Safety Executive'
in the UK into possible dangers from soldering in a service environment.
During the test I asked what sort of lead levels were dangerous, they
replied that the health risks being assessed were from the FLUX!! not
the lead!. Apparently the fumes from the flux can cause asthma, although
they did admit that in all of the service departments they tested there
were no asthma sufferers (nor any how had left because of breathing
problems). As far as the UK authorities are concerned there is no danger
from soldering using lead/tin solder - only the flux, hence the recent
surge of new fluxes (which don't work well!).
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2000\09\09@135501 by Dan Michaels

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NIgel Goodwin wrote:
........
>problems). As far as the UK authorities are concerned there is no danger
>from soldering using lead/tin solder - only the flux, hence the recent
>surge of new fluxes (which don't work well!).


However, I have heard [ie, this is total hearsay] that incidental
lead contact in not too bad for "adults", but is quite bad for kids.
Just don't eat after handling it, without washing up. And you
certainly wouldn't want to setup your solder station in the
nursery. Hearsay.

[and as Olin, I believe, said - remember the Roman empire did
invent great engineering systems to water their cities, but
unfortunately lined the conduits with lead - today, the empire
is gone, but you can still see the lead linings all over southern
europe].

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2000\09\09@141129 by staff

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More about lead, Australia used lead pipes for many years
for domestic water pipes, still common in some areas. I prefer
the taste and clarity of water from lead pipes, most of the
newer stainless steel pipes put an awful bitter metallic taste
in the water, with white oxides suspended and who knows
what heavy metals leach from the stainless steel. At least with
lead you know where you stand. They say very little lead commutes
into the water, very low oxidation in the pipes compared to
alloys like stainless and regular steels.

I have breathed lead solder fumes for 25 years, and discussed
this with my doctor. He told me of another of his patients who was
a stained-glass maker who melts lead in large quanities and
breathed much more fumes than me, who had a blood test for lead
levels in the blood. Apparently his test showed no noticable
lead levels over the norm. I know this is hearsay but I trust
my Doc's professionalism and have felt a bit easier about
soldering after that.

I am willing to revise my opinions however, just prefer
facts to scare mongering. Just about anything is bad for you
in large enough quantities. Especially most household metals.
Do you drink acidic drinks from alluminium cans? Now that is
scary.



Dan Michaels wrote:
{Quote hidden}

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2000\09\09@154000 by Dan Michaels

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Roman Black wrote:
.........
>I am willing to revise my opinions however, just prefer
>facts to scare mongering. Just about anything is bad for you
>in large enough quantities. Especially most household metals.
>Do you drink acidic drinks from alluminium cans? Now that is
>scary.
>

Did your doctor have anything to say about children and lead?

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2000\09\09@154828 by Dan Michaels

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Roman Black wrote:
.........
>I am willing to revise my opinions however, just prefer
>facts to scare mongering. Just about anything is bad for you
>in large enough quantities. Especially most household metals.
>Do you drink acidic drinks from alluminium cans? Now that is
>scary.
>

Did your doctor have anything to say about children and lead?

JFTHOI, I did a search on "lead" on US Consumer Product Safety
Commission site:

http://www.cpsc.gov/

It returned the following - first 10 out of 297 [OTOH, america
*is* certainly over-regulated]:


1. Codification of Guidance Policy on Lead in Consumer Products
Abstract: Federal Register: December 22, 1998 (Volume 63, Number 245)
[Rules and Regulations] [Page 70648-70649] From the Federal Register
Online via GPO Access [wais.access.gpo.gov] [DOCID:fr22de98-8] -
CONSUMER PRODUCT SAFETY COMMISSION 16 CFR Part 1500 Codification of
Guidance Policy on Lead in Consumer Pr

2. Guidance for Lead (Pb) in Consumer Products
Abstract: Washington, D.C. 20207. Guidance for Lead (Pb) in Consumer
Products Summary: The U.S. Consumer Product Safety Commission issues
this guidance to manufacturers, importers, distributors, and retailers
to protect children from hazardous exposure to lead in consumer
products.1 The Commission identifies

3. Crayons Recalled by Concord Enterprises
Abstract: NEWS from CPSC. U.S. Consumer Product Safety Commission. CPSC
And Concord Enterprises Announce Recall Of Certain Crayons Because Of
Lead Poisoning Hazard. Office of Information and Public Affairs.
Washington, DC 20207. FOR IMMEDIATE RELEASE. CONTACT: Ken Giles. March
22, 1994. 301) 504-0580, Ext. 1184.

4. CPSC Finds Lead Poisoning Hazard for Young Children in Imported Vinyl
Miniblinds
Abstract: NEWS from CPSC. U.S. Consumer Product Safety Commission. CPSC
Finds Lead Poisoning Hazard for Young Children in Imported Vinyl
Miniblinds. Office of Information and Public Affairs. Washington, DC
20207. FOR IMMEDIATE RELEASE. CONTACT:Kathleen Begala. June 25, 1996.
301) 504-0580 Ext. 1193. Release # 96-150.

5. Toy Manufacturers Agree to Rid Products of Lead
Abstract: NEWS from CPSC. U.S. Consumer Product Safety Commission. Toy
Manufacturers Agree to Rid Products of Lead. Office of Information and
Public Affairs. Washington, DC 20207. FOR IMMEDIATE RELEASE. CONTACT:
Nychelle Fleming. August 20, 1998. 301) 504-0580 Ext.1192. Release #
98-154. WASHINGTON, D.C. - The To

6. CPSC Lead-in-Paint Activities Reduce Consumer Exposure to Lead
Abstract: CPSC Lead-in-Paint Activities Reduce Consumer Exposure to
Lead. Extensive regulatory and educational efforts undertaken since the
late 1970s, including CPSC's 1978 ban of most paints containing 0.06
percent or more lead, have dramatically reduced blood lead levels
nationwide. Blood lead estimates from the most re

7. Questions and Answers: Lead Paint on Public Playground Equipment
Abstract: Consumer Product Safety Commission. Questions and Answers:
Lead Paint on Public Playground Equipment. Prepared by CPSC Staff
October 1, 1996 Question: Why is the CPSC concerned about lead paint on
playground equipment? Response: While deteriorating lead paint in homes
poses the most significant lead r

8. CPSC Staff Recommendations for Identifying and Controlling Lead Paint
on Public Playground Equipment
Abstract: Consumer Product Safety Commission. CPSC Staff Recommendations
for Identifying and Controlling Lead Paint on Public Playground
Equipment. October 1996. I. Introduction The purpose of this document is
to: 1) report U.S. Consumer Product Safety Commission (CPSC) staff
findings that indicate a potential

9. CONSUMER PRODUCT SAFETY COMMISSION STAFF RECOMMENDATIONS FOR
IDENTIFYING AND CONTROLLING LEAD PAINT ON PUBLIC PLAYGROUND EQUIPMENT
Abstract: CONSUMER PRODUCT SAFETY COMMISSION STAFF RECOMMENDATIONS FOR
IDENTIFYING AND CONTROLLING LEAD PAINT ON PUBLIC PLAYGROUND EQUIPMENT.
EXECUTIVE SUMMARY. HEALTH RISKS. CPSC STAFF RECOMMENDATIONS. A. Lead
Hazard Assessment. B. Controlling the Lead Hazard. CONSUMER PRODUCT
SAFETY COMMISSION STAFF RECOMMEND

10. Lead Poisoning Hazard for Young Children on Public Playground
Equipment
Abstract: NEWS from CPSC. U.S. Consumer Product Safety Commission. CPSC
Finds Lead Poisoning Hazard for Young Children on Public Playground
Equipment. Office of Information and Public Affairs. Washington, DC
20207. FOR IMMEDIATE RELEASE. CONTACT: Kathleen Begala. October 1, 1996.
301) 504-0580 Ext. 1193. Release # 97-001.

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2000\09\09@174343 by Robert A. LaBudde

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At 09:40 AM 9/9/00 -0400, you wrote:
>Hi,
>
>Has anyone looked into the effect of lead vapor emmited during soldering?
>I heared lead sublimes and therefore will be around if there are any sources
>around, i.e-computers, TVs, solder spool, etc.

1. There shouldn't be much lead vapor. You shouldn't be heating the solder
much higher than the melting point. Lead (and tin, for that matter), don't
sublime, so the vapor pressure should be fairly low at soldering
temperatures (~ 400 C).

2. Lead is somewhat soluble, but still accumulates in the body to some
extent. It interferes with neural development and injures the liver, where
it accumulates.

3. Children are more at risk from lead poisoning than adults since they are
still undergoing neural growth. They also are easily poisoned by eating
paint chips with lead oxide.

4. Specific types of heavy metal compounds are much more dangerous than
others. Soluble compounds get into the bloodstream quickly.


================================================================
Robert A. LaBudde, PhD, PAS, Dpl. ACAFS  e-mail: ralspamKILLspamlcfltd.com
Least Cost Formulations, Ltd.            URL: http://lcfltd.com/
824 Timberlake Drive                     Tel: 757-467-0954
Virginia Beach, VA 23464-3239            Fax: 757-467-2947

"Vere scire est per causas scire"
================================================================

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2000\09\10@041713 by staff

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Dan Michaels wrote:
>

> Did your doctor have anything to say about children and lead?
>

No. But i remember a big fuss here to re-paint a lot of schools
to get rid of the lead paint. Seemed a prtty important issue. I
think lead paint is more dangerous as it flakes into tiny bits
with a high surface area that oxidise a great deal. I think the
contact with lead oxide is probably more dangerous than conact
with lead itself. Most metals are not biologically available in
their normal state, ie your body can't absorb them until they
are a oxide or sulphate or something. Like magnesium or iron
supplements, if you just ate iron dust or magnesium dust you
wouldn't absorb any. By the same logic, contact or even eating
lead probably wouldn't get into your blood unless it was lead
sulphide of something. I think that's why lead paint is the worst
type of lead for lead poisoning.

But how does that affect soldering? I often spend a few hours
a day with my face over a hot soldering iron, and who knows
more about the flux?

Isn't there a new lead-free solder? I have seen it in the EE
catalogues but never tried any.

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2000\09\11@053907 by Alan B. Pearce

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>Lead (and tin, for that matter), don't
>sublime, so the vapor pressure should be fairly low at soldering
>temperatures (~ 400 C).

I think you will find that tin does sublime to some degree. I have had a tiny
bit of experience working on vacuum systems (in this case beamlines for research
use) and one of the things to avoid was tin. A typical grounding lug would be
sandblasted to bare copper for use in the vacuum because the tin coating would
release ions into the vacuum.

This may be more a case of how tin behaves in a vacuum than a real subliming of
it, but do be aware it may be a problem.

With regards to lead, I believe one of the effects of a build up of lead in a
human, is problems with impotency.

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2000\09\11@055945 by xandinho

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>With regards to lead, I believe one of the effects of a build up of lead in a
>human, is problems with impotency.

       Ops :o(


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       All the best!!!
       Alexandre Souza
       .....xandinhoKILLspamspam.....interlink.com.br

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2000\09\11@164805 by Ethan Swint

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It's the zinc in tin (or brass) that causes problems with vaporization, but
only around 10^-3 or 10^-5 torr and lower.  If you have a couple hundred
volts running through the system, you get a very nice lightning display
along the vapor trails!  (Not that I've done this personally.  I've just
heard.)

Ethan

{Original Message removed}

2000\09\12@014313 by Dr. Imre Bartfai

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Hi,

I agree lead and other heavy metals (Ni, Cd, Ba, even Hg) are dangerous in
ionized state. According to this, I recall an interesting story:

here in Hungary, the "paprika" (approx. red chili pepper) powder is VERY
popular and used daily in cooking different dishes. This gives also nice
red colour to them.

3 years ago or so, there was a bad harvest, so "paprika" was imported even
smuggled. However, that sort was not so nice red so unresponsible people
have added lead oxyde to colour them. Consequently, a lot of customers
were intoxicated in a dangerous manner that hospital treatment was
necessary. Ridiculous, the symptoms were not defined (different pains,
anaemia, tiredness). Only a causal blood control of lead level has
discovered the true reason.

Regards,
Imre

On Sun, 10 Sep 2000, Roman Black wrote:

{Quote hidden}

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